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ʻIke ʻoe e pili ana i ka Photoinitiator

He aha nā photoinitiators a pehea ka nui o kāu ʻike e pili ana i nā photoinitiators? ʻO nā Photoinitiators kahi ʻano o ka pūhui e hiki ke hoʻomoʻi i ka ikehu ma kekahi lōʻihi nalu i ka ʻāpana ultraviolet (250-420nm) a i ʻole ʻike ʻia (400-800nm), e hoʻohua i nā radical manuahi, nā cations, a pēlā aku, a pēlā e hoʻomaka ai ka monomer polymerization, crosslinking, a me ka ho'ōla . Eia nō naʻe, ʻokoʻa nā lōʻihi nalu i lawe ʻia e nā photoinitiators like ʻole.

Hiki ke hoʻokaʻawale ʻia ka hoʻokaʻawale ʻana o nā photoinitiators i ʻelua mau ʻāpana: nā radical manuahi a me nā ʻano ionic. Hiki ke hoʻokaʻawale ʻia nā radical manuahi i ke ʻano I a me ke ʻano II; Hiki ke hoʻokaʻawale ʻia nā ʻano Ionic i nā ʻano cationic a me nā anionic. ʻO ka photoinitiator ka wahi hoʻomaka o ka hoʻokumu ʻana, a ʻo kona hoʻohana hope ʻia e hoʻopili ʻia e nā koi hana a me ka ʻōnaehana hoʻonohonoho. Aia wale nō ka photoinitiator kūpono loa, ʻaʻohe photoinitiator maikaʻi loa.

Aia nā Photoinitiators i uka o ke kaulahao ʻoihana. ʻO nā mea maka i loko o ke kaulahao ʻoihana hoʻomaʻamaʻa UV ka mea maʻamau a me nā kemika kūikawā, me nā photoinitiators aia i luna o ke kaulahao ʻoihana. Hiki ke hoʻohana ʻia ka moʻo o nā pūhui thiol e like me nā mea maka no nā photoinitiators, a hoʻohana nui ʻia i nā ʻano lāʻau lapaʻau a me ka hana pesticide; Hoʻohana ʻia nā Photoinitiators ma nā ʻano like ʻole e like me nā photoresists a me nā mea kemika kākoʻo, nā uhi UV, nā inika UV, a me nā mea ʻē aʻe, me nā noi terminal e pili ana i nā huahana uila, nā mea hoʻonaninani hale a me nā mea kūkulu hale, nā lāʻau lapaʻau a me nā lāʻau lapaʻau, etc.

Aia nā ʻano like ʻole o nā photoinitiators me ka nui o ka hoʻohana ʻana, no laila pehea mākou e koho ai iā lākou? A laila, e haʻi wau iā ʻoe pehea e koho ai i nā huahana i ʻike pinepine ʻia.

ʻO ka mea mua, makemake wau e hoʻolaunamea hoʻomaka kiʻi 819, hiki ke hoʻohana ʻia no ka uhi ʻia ʻana o nā kala ʻulaʻula UV. ʻO nā uhi UV, ma muli o kā lākou hana maikaʻi loa a me ka hana maikaʻi ʻana, ua hoʻohana nui ʻia i nā pūpū plastik o nā huahana uila a me nā mea pono hale. Eia naʻe, ʻaʻole maikaʻi ka paʻa paʻa ʻana o ka uhi ʻana o UV ma hope o ke kala ʻana, e hopena i ka hoʻopili ʻana i nā kiʻiʻoniʻoni maikaʻi ʻole a me ka hoʻopuehu maikaʻi ʻana a me ka hoʻonohonoho ʻana o nā puaʻa e nā resins UV, e pili nui ana i ke ʻano o nā uhi, no laila, ʻo ke kaʻina hana kuʻuna e hoʻopili mua i ka solvent. kumu kala no ka kala ʻana, a laila e hoʻopili i ka varnish UV ma hope o ka kuke ʻana e hoʻomaikaʻi i nā ʻano kino like ʻole o ka ʻili kiʻi pena.

Mea hoʻomaka kiʻi 184He kiʻi paʻi kiʻi paʻa paʻa ʻano ʻano radical manuahi (I) maikaʻi a melemele me ka maikaʻi o ka manawa mālama lōʻihi, kiʻekiʻe ka hoʻomaka ʻana, a me ka laulā UV absorption. Hoʻohana nui ʻia ia no ka hoʻōla ʻana o UV i nā prepolymers unsaturated (e like me nā esters acrylic) me nā monomers vinyl a me nā oligomers hoʻokahi a i ʻole, a he kūpono loa ia no nā uhi a me nā inika e koi ana i ka pae melemele kiʻekiʻe.

Photoinitiator TPO-Lhe ʻano wai photoinitiator, i hoʻohana ʻia i ka ʻōnaehana hoʻokumu me ka haʻahaʻa melemele a me ka ʻala haʻahaʻa. Hoʻohana maʻamau ia i ka inika paʻi kiʻi silika, ka inika paʻi paʻi Planographic, ka inika paʻi flexographic, photoresist, varnish, paʻi paʻi a me nā māla ʻē aʻe.

ʻO kamea hoʻomaka kiʻi TPOHoʻohana nui ʻia i nā ʻōnaehana keʻokeʻo, a hiki ke hoʻohana ʻia i nā uhi hoʻōla UV, paʻi inika, UV curing adhesives, Optical fiber coatings, photoresists, photopolymerization plates, stereolithographic resins, composites, tooth fillers, etc.

ʻO Photoinitiator 2959 he photoinitiator maikaʻi ʻole melemele me ka hana kiʻekiʻe, haʻahaʻa haʻahaʻa, ʻaʻole melemele, haʻahaʻa volatility, insensitivity i ka polymerization oxygen, a me ka maikaʻi o ka mālama ʻana i ka ʻili. ʻO nā pūʻulu hydroxyl kūʻokoʻa i hiki ke hoʻoheheʻe ʻia i loko o nā uhi wai. ʻOi aku ka maikaʻi no nā esters acrylic e pili ana i ka wai a me nā polyesters unsaturated. ʻO Photoinitiator 2959 kekahi mea hoʻopili i ʻae ʻia e ka ʻōnaehana hōʻoia FDA no ka launa ʻole me ka meaʻai.

BenzophenoneʻO ia ka mea i hoʻohana nui ʻia i nā ʻōnaehana hoʻōla UV radical manuahi e like me nā uhi, inika, adhesives, a me nā mea ʻē aʻe. ʻO kēia huahana he mea hoʻopololei styrene polymerization a me ka fixative ʻala, hiki ke hāʻawi i ka ʻala i kahi ʻono ʻono, a hoʻohana nui ʻia i ka ʻala a me ke kopa.

ʻO nā huahana e like me nā photoinitiators he ultraviolet absorbers. I kekahi manawa, ʻaʻole hiki i nā kānaka ke hoʻokaʻawale i waena o nā mea ʻelua.Nā mea hoʻopau UVhiki ke pani i nā photoinitiators. No ka mea, ʻo ka UV absorbers ka mea i hoʻohana nui ʻia o ka stabilizer māmā a hiki ke hoʻopili a hoʻololi paha i nā photoinitiators no ka hoʻohana ʻana, a ʻoi aku ka maikaʻi o kā lākou hana. Hoʻohana pono ʻia nā Photoinitiators no ka paʻi kiʻi ʻana, no ka inika, ka uhi, a hiki ke hoʻohana ʻia i nā ʻoihana ʻenehana a me nā ʻenehana uila. Loaʻa i ka UV absorbers ka nui o ka hoʻohana ʻana, hoʻohana nui ʻia i nā mea hoʻonaninani me nā koi kiʻekiʻe. I kēia manawa, ʻoi aku ka kiʻekiʻe o ke kumukūʻai o ka ultraviolet absorbers, ʻoiai he haʻahaʻa haʻahaʻa nā photoinitiators. Hiki iā ʻoe ke koho i nā huahana e pili ana i kāu pono ponoʻī.

He mea hana hoʻomaka ʻoihana mākou. Ma kahi o nā huahana i ʻōlelo ʻia ma luna nei, loaʻa iā mākou nā huahana like ʻole:

CAS No. Inoa Huahana
162881-26-7 Phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide
947-19-3 1-Hydroxycyclohexyl phenyl ketone
84434-11-7 Ethyl (2,4,6-trimethylbenzoyl) phenylphosphinate
75980-60-8 Diphenyl(2,4,6-trimethylbenzoyl) phosphine oxide
125051-32-3 Bis(eta.5-2,4-cyclopentadien-1-yl)-bis
[2,6-difluoro-3- (1H-pyrrol-1-yl)phenyl]titanium
75980-60-8 2,4,6-Trimethyl benzoyldiphenyl phosphine oxide
162881-26-7 Bis(2,4,6-trimethylbenzoyl) phenylphosphine oxide
84434-11-7 Ethyl(2,4,6-trimethylbenzoyl)phenylphosphinate
5495-84-1 2-Isopropylthioxanthone
82799-44-8 2,4-Diethylthioxanthone
71868-10-5 2-Methyl-1- [4- (methylthio)phenyl]-2-morpholinopropane-1-kahi
119313-12-1 2-Benzyl-2-dimethylamino-1- (4-morpholinophenyl)butanone
947-19-3 1-Hydroxy-Cyclohexyl Phenyl Ketone
7473-98-5 2-Hydoy-2-mey-1-phenyppae–hoʻokahi
10287-53-3 Ethyl4-dimethylaminobenzoate
478556-66-0 [1-9-e kou-6-2-methybenzoycabazo-3-yethylideneamino] acetate
77016-78-5 3-benzo-7-dehyamnocoumrn
3047-32-3 3-Ethyl-3- (hydroxymethyl)oxetane
18934-00-4 3,3′-[Oxybis(methylene)]bis[3-ethiloxetane]
2177-22-2 3-Ethyl-3- (chloromethyl)oxetane
298695-60-0 3-Ethyl-3-[(2-ethylhexyloxy)methyl]oxetane
18933-99-8 3-Ethyl-3-[(benzyloxy)methyl]oxetane
37674-57-0 3-Ethyl-3- (methacryloyloxymethyl)oxetane
41988-14-1 3-Ethyl-3- (acryloyloxymethyl)oxetane
358365-48-7 Oxetane Biphenyl
18724-32-8 Bis[2-(3,4-epoxycyclohexyl)ethy]tetramethyldisiloxane
2386-87-0 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
1079-66-9 Chlorodiphenyl phosphine
644-97-3 Dichlorophenylphosphine
938-18-1 2,4,6-Trimethylbenzoyl chloride
32760-80-8 Cyclopentadienyliron(i) hexa-fluorophosphate
100011-37-8 Cyclopentadienyliron(ii) hexa-fluoroantimonate
344562-80-7
& 108-32-7
4-Isobutylphenyl-4′-methylphenyliodonium
hexafluorophosphate & propylene carbonate
71786-70-4
& 108-32-7
Bis(4-dodecylphenyl)iodonium hexaflurorantimonate & propylene carbonate
121239-75-6 (4 -Ocyoxyphenyphenyodonum hexafluoroantimonate
61358-25-6 Bis(4-tert-butylphenyl)iodonium hexafluorophosphate
60565-88-0 Bis(4-methylphenyl)iodonium hexafluorophosphate
74227-35-3
& 68156-13-8
& 108-32-7
Huipuia Sulfonium Hexafluorophosphate & Propylene carbonate
71449-78-0
&89452-37-9
& 108-32-7
Huihui Sulfonium Hexafluoroantimonate & Propylene carbonate
203573-06-2   
42573-57-9 2-2- 4-Mehoxypheny -2-yvny-46-bs (trichloromethyl)1,3,5-triazine
15206-55-0 Methyl benzoylformate
119-61-9 Benzophenone
21245-02-3 2-Ethylhexyl 4-dimethylaminobenzoate
2128-93-0 4-Benzoylbiphenyl
24650-42-8 Photoinitiator BDK
106797-53-9 2-Hydroxy-4′-(2-hydroxyethoxy)-2-methylpropiophenone
83846-85-9 4-(4-Methylphenylthio)benzophenone
119344-86-4 PI379
21245-01-2 Padimate
134-85-0 4-Chlorobenzophenone
6175-45-7 2,2-Diethoxyacetophenone
7189-82-4 2,2′-Bis(2-chlorophenyl)-4,4′,5,5′-tetraphenyl-1,2′-biimidazole
10373-78-1 Photoinitiator CQ
29864-15-1 2-Methyl-BCIM
58109-40-3 Photoinitiator 810
100486-97-3 TCDM-HABI
813452-37-8 OMNIPOL TX
515136-48-8 Omnipol BP
163702-01-0 KIP 150
71512-90-8 Photoinitiator ASA
886463-10-1 Photoinitiator 910
1246194-73-9 Photoinitiator 2702
606-28-0 Methyl 2-benzoylbenzoate
134-84-9 4-Methylbenzophenone
90-93-7 4,4′-Bis(diethylamino) benzophenone
84-51-5 2-Ethyl anthraquinone
86-39-5 2-Chlorothioxanthone
94-36-0 Benzoyl peroxide
579-44-2/119-53-9 ʻO Benzoin
134-81-6 Benzil
67845-93-6 UV-2908

Ka manawa hoʻouna: ʻAukake-04-2023